Fluoride Ion as Ligand and Hydrogen Bond Acceptor: Crystal Structures of Two Dinuclear CuII Complexes Built on a Diazecine Template
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Fluoride Ion as Ligand and Hydrogen Bond Acceptor: Crystal Structures of Two Dinuclear CuII Complexes Built on a Diazecine Template
Two dinuclear Cu complexes based on a diazecine ligand were characterized by X-ray diffraction, one of which includes the rare Cu–F bond, resulting from dissociation of a BF4 ion. The F ligands actively participate in the crystal structure, behaving as acceptors for hydrogen bonding.
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ژورنال
عنوان ژورنال: Crystals
سال: 2012
ISSN: 2073-4352
DOI: 10.3390/cryst2031357